No, because I have no idea how you set pyTivo up on your system. But Spotlight can. You know, the magnifying glass, top right?
Before you do that, though: Are you using pyTivo, or pyTivo
X? If it's the latter, you probably want to use its own method of configuration.
You can also use the web interface (
http://localhost:9032/ ) rather than editing the pyTivo.conf file.